Issue 0, 1966

H0 measurements in some salt–acid mixtures of fixed total anion concentration

Abstract

The Hammett acidity function, H0, is reported for 3 and 6 molal mixtures of perchloric, hydrochloric, and nitric acids with their lithium and sodium salts. As expected theoretically, perchlorate mixtures containing lithium exhibit a much closer proportionality between h0 and acid content than those containing sodium; but the opposite is true of the chloride and nitrate systems.

Article information

Article type
Paper

J. Chem. Soc. B, 1966, 343-345

H 0 measurements in some salt–acid mixtures of fixed total anion concentration

J. S. Day and P. A. H. Wyatt, J. Chem. Soc. B, 1966, 343 DOI: 10.1039/J29660000343

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