A three-dimensional X-ray crystal structure analysis has shown dimethylaminoboron difluoride to be dimeric, [(CH3)2NBF2]2. The molecule, which has symmetry mmm, consists of a 4-membered (BN)2 ring with substituents above and below the plane of the ring. The methyl groups are fully staggered with respect to the B–N–B framework.
A. C. Hazell, J. Chem. Soc. A, 1966, 1392 DOI: 10.1039/J19660001392
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