Issue 0, 1966

Preparation and pyrolysis of tetramethyltetrazene–beryllium dialkyl complexes

Abstract

The reactions of Me2NN[double bond, length as m-dash]NNMe2 with Et2Be,Pri2Be, and But2Be yielded 1:1 dative-bonded complexes and complexes with two beryllium alkyls per tetramethyltetrazene, the latter being more stable.

Pyrolysis of the 2:1 compounds near 200°C has resulted in the formation of low molecular weight polymers containing BeH and RBe, perhaps serving as bridging groups, and Me2NN[double bond, length as m-dash]NNMe2 apparently serving as a linking agent for the beryllium atoms.

Article information

Article type
Paper

J. Chem. Soc. A, 1966, 711-713

Preparation and pyrolysis of tetramethyltetrazene–beryllium dialkyl complexes

N. R. Fetter, J. Chem. Soc. A, 1966, 711 DOI: 10.1039/J19660000711

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