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Issue 2, 2018
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Novel perylene diimide-based polymers with electron-deficient segments as the comonomer for efficient all-polymer solar cells

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Abstract

Two novel acceptor–acceptor (A–A) type polymer electron acceptors, PPDI-DTBT and PFPDI-DTBT, which contain perylene diimide (PDI) and fused PDI (FPDI) with electron deficient 4,7-dithienyl-2,1,3-benzothiadiazole (DTBT) units, respectively, are designed and synthesized to investigate their application in all-polymer solar cells (all-PSCs). With a narrow band-gap polymer, PTB7-Th, as the polymer donor, all-PSCs based on PTB7-Th:PPDI-DTBT showed a promising power conversion efficiency (PCE) of 4.07%, whereas the photovoltaic performance of PTB7-Th:PFPDI-DTBT was further improved with a PCE of 6.23%, which is the best device performance (ca. 75% higher) for all-PSCs of PDI-based A–A type polymer acceptors reported so far. Their optical, electrochemical, photoluminescence and charge transport properties were investigated to illustrate the difference in the photovoltaic performance. The results open a design strategy of PDI-based A–A type polymer electron acceptors through modifying the polymer structure to restrict molecular chain interactions to achieve high performance all-PSCs.

Graphical abstract: Novel perylene diimide-based polymers with electron-deficient segments as the comonomer for efficient all-polymer solar cells

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Supplementary files

Article information


Submitted
11 Nov 2017
Accepted
01 Dec 2017
First published
04 Dec 2017

J. Mater. Chem. A, 2018,6, 414-422
Article type
Paper

Novel perylene diimide-based polymers with electron-deficient segments as the comonomer for efficient all-polymer solar cells

M. Liu, J. Yang, Y. Yin, Y. Zhang, E. Zhou, F. Guo and L. Zhao, J. Mater. Chem. A, 2018, 6, 414
DOI: 10.1039/C7TA09930D

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