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Issue 22, 2015
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Novel understanding of carbothermal reduction enhancing electronic and ionic conductivity of Li4Ti5O12 anode

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Abstract

Spinel Li4Ti5O12 performance highly depends on both the electronic and ionic conductivity, however, developing a low-cost strategy to improve its electronic and ionic conductivity still remains challenging. In this study, a facile cost-saving carbothermal reduction method is introduced to synthesize the microscaled spinel Li4Ti5O12 particles with the surface modification of Ti(III) using anatase–TiO2, Li2CO3, and acetylene black (AB) as precursors. Remarkably, this ingenious design can easily eliminate the influence of the residual carbon, and thus makes it possible to individually study the effect of the Ti(III) on the bulk Li4Ti5O12. To reveal the role of the Ti(III), the electronic conductivity and lithium-ion diffusion coefficient of the as-prepared materials were measured using a direct volt-ampere method, electrochemical impedance spectroscopy (EIS), and cyclic voltammetry (CV). The results indicate that the carbothermal reduction leads to the increased electronic and ionic conductivity of the spinel Li4Ti5O12. As a result, the modified Li4Ti5O12 exhibits an enhanced cyclic stability, improved rate capability, and high Coulombic efficiency. The carbothermal reduction mechanism discreetly clarified in this study is beneficial to improving Li4Ti5O12 performance for further commercial applications.

Graphical abstract: Novel understanding of carbothermal reduction enhancing electronic and ionic conductivity of Li4Ti5O12 anode

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Article information


Submitted
03 Feb 2015
Accepted
01 Mar 2015
First published
02 Mar 2015

J. Mater. Chem. A, 2015,3, 11773-11781
Article type
Paper
Author version available

Novel understanding of carbothermal reduction enhancing electronic and ionic conductivity of Li4Ti5O12 anode

B. Yan, M. Li, X. Li, Z. Bai, J. Yang, D. Xiong and D. Li, J. Mater. Chem. A, 2015, 3, 11773
DOI: 10.1039/C5TA00887E

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