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Issue 27, 2016
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Uniform distribution of graphene oxide sheets into a poly-vinylidene fluoride nanoparticle matrix through shear-driven aggregation

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Abstract

A general methodology has been developed for preparing nanocomposites with uniform, random distribution of fillers in polymer matrices, purely based on intense shear-driven aggregation, while avoiding filler aggregation. This procedure is demonstrated for a binary colloid composed of graphene oxide (GO) sheets and poly-vinylidene fluoride (PVDF) nanoparticles (NPs), both negatively charged and stable at rest. On the other hand, the PVDF NPs are shear-active (i.e. aggregation occurs under intensive shear), while the GO sheets are shear-inactive. It is found that when the two suspensions are mixed and the resulting binary colloid is forced to pass through a microchannel (MC) device (at a very high shear rate, G = 1.2 Ɨ 106 sāˆ’1), the shear-inactive GO sheets are captured and well distributed inside the PVDF NP clusters or gels. In addition, it is shown that in order to have 100% capture efficiency for the GO sheets, a minimum solid content of the binary colloid is required, which can be identified experimentally as the minimum leading to gelation after passing through the MC only one time.

Graphical abstract: Uniform distribution of graphene oxide sheets into a poly-vinylidene fluoride nanoparticle matrix through shear-driven aggregation

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Publication details

The article was received on 03 Mar 2016, accepted on 12 Jun 2016 and first published on 13 Jun 2016


Article type: Paper
DOI: 10.1039/C6SM00551A
Soft Matter, 2016,12, 5876-5882

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    Uniform distribution of graphene oxide sheets into a poly-vinylidene fluoride nanoparticle matrix through shear-driven aggregation

    X. Sheng, D. Xie, X. Zhang, L. Zhong, H. Wu and M. Morbidelli, Soft Matter, 2016, 12, 5876
    DOI: 10.1039/C6SM00551A

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