Issue 50, 2014
From the journal:

RSC Advances

Synthesis of novel ferrocenyl N/O-heterocycles, chiral P,N-ligand and α-dehydro-β-amino acid derived short peptides from Morita–Baylis–Hillman adducts of ferrocenealdehyde†

Suchithra Madhavan,a   Ponnusamy Shanmugam*b  and  Ramavarma Luxmi Varmaa  

* Corresponding authors

a Organic Chemistry Section, National Institute for Interdisciplinary Science and Technology (CSIR-NIIST), Trivandrum-695 019, India

b Organic Chemistry Division, Central Leather Research Institute (CSIR-CLRI), Adyar, Chennai-600020, India
E-mail: shanmu196@rediffmail.com
Fax: +91-44-24911589
Tel: +91-044-24913289

Abstract

The ‘golden triangle’ of Fc, OH/NH, COO moieties created by classical/aza-MBH reaction of ferrocenealdehyde has been exploited for the first time for the synthesis of novel multisubstituted ferrocenyl N/O heterocycles, chiral P,N ligands and ferrocenyl α-dehydro-β-peptides.

Graphical abstract: Synthesis of novel ferrocenyl N/O-heterocycles, chiral P,N-ligand and α-dehydro-β-amino acid derived short peptides from Morita–Baylis–Hillman adducts of ferrocenealdehyde

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Article information

DOI
https://doi.org/10.1039/C4RA02201G
Article type
Communication
Submitted
13 Mar 2014
Accepted
27 May 2014
First published
28 May 2014

RSC Adv., 2014,4, 26211-26214

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Synthesis of novel ferrocenyl N/O-heterocycles, chiral P,N-ligand and α-dehydro-β-amino acid derived short peptides from Morita–Baylis–Hillman adducts of ferrocenealdehyde

S. Madhavan, P. Shanmugam and R. L. Varma, RSC Adv., 2014, 4, 26211 DOI: 10.1039/C4RA02201G

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