The acid-catalysed hydrolyses of some N-(para-substituted phenyl)propane-1,3-sultams have been studied in aqueous acidic solutions. The rate maxima observed are shown to be consistent with an A-2 mechanism in which extensive protonation of the substrate occurs. Values of pKBH+ for the sultams have been determined.
Y. Bekdemir, J. G. Tillett and R. I. Zalewski, J. Chem. Soc., Perkin Trans. 2, 1993, 1643 DOI: 10.1039/P29930001643
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...