Issue 9, 1993

Preparation, properties and structure of crystalline silver ketenide (µ-oxoethenylidene disilver) and its pyridine complex

Abstract

Silver ketenide of empirical formula Ag2C[double bond, length half m-dash]C[double bond, length half m-dash]O is obtained by direct reaction of ketene or an in situ source of ketene such as acetic anhydride, isopropenyl acetate, vinyl acetate or phenyl acetate with certain silver salts, normally in the presence of a base.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1993, 1631-1642

Preparation, properties and structure of crystalline silver ketenide (µ-oxoethenylidene disilver) and its pyridine complex

E. T. Blues, D. Bryce-Smith, R. Shaoul, H. Hirsch and M. J. Simons, J. Chem. Soc., Perkin Trans. 2, 1993, 1631 DOI: 10.1039/P29930001631

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