Issue 24, 2002
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

Stereocontrolled synthesis of glucosidic damascenone precursors

Yumiko Yamano,a   Yasuko Watanabe,a   Naoharu Watanabeb  and  Masayoshi Ito*a  

* Corresponding authors

a Kobe Pharmaceutical University, Motoyamakita-machi, Higashinada-ku, Kobe 658-8558, Japan

b Faculty of Agriculture, Shizuoka University, Ohya, Shizuoka 422-8529, Japan

Abstract

A stereocontrolled synthesis of optically active β-D-glucopyranosides 7–10 and 11–14, glucosidic damascenone precursors, was accomplished utilizing an asymmetric transfer hydrogenation to α,β-acetylenic ketones catalyzed by chiral ruthenium complexes as the key step.

Graphical abstract: Stereocontrolled synthesis of glucosidic damascenone precursors

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Article information

DOI
https://doi.org/10.1039/B208758H
Article type
Paper
Submitted
06 Sep 2002
Accepted
22 Oct 2002
First published
15 Nov 2002

J. Chem. Soc., Perkin Trans. 1, 2002, 2833-2844

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Stereocontrolled synthesis of glucosidic damascenone precursors

Y. Yamano, Y. Watanabe, N. Watanabe and M. Ito, J. Chem. Soc., Perkin Trans. 1, 2002, 2833 DOI: 10.1039/B208758H

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