Issue 24, 2002

Palladium(0) catalysed and copper(i) promoted reactions of the secondary zinc reagent derived from L-threonine

Abstract

C-3 epimeric secondary zinc reagents 2a/b were prepared from either diastereoisomeric iodide 3a or 3b using DMF as solvent, and characterised by 1H NMR methods. Palladium catalysed cross couplings and copper promoted allylations yielded protected β-methyl substituted amino acids.

Graphical abstract: Palladium(0) catalysed and copper(i) promoted reactions of the secondary zinc reagent derived from L-threonine

Article information

Article type
Paper
Submitted
06 Sep 2002
Accepted
22 Oct 2002
First published
19 Nov 2002

J. Chem. Soc., Perkin Trans. 1, 2002, 2845-2850

Palladium(0) catalysed and copper(I) promoted reactions of the secondary zinc reagent derived from L-threonine

I. Wilson and R. F. W. Jackson, J. Chem. Soc., Perkin Trans. 1, 2002, 2845 DOI: 10.1039/B208667K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements