Issue 22, 2002
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

Asymmetric synthesis of C2-symmetric 5,6-bis(benzyloxy)cyclohexa-1,3-diene and a tricarbonyliron complex

Akiko Watanabe,a   Takao Kamahori,a   Mariko Asoa  and  Hiroshi Suemune*a  

* Corresponding authors

a Graduate School of Pharmaceutical Sciences, Kyushu University, Fukuoka 812-8582, Japan

Abstract

The C2-symmetric 5,6-bis(benzyloxy)cyclohexa-1,3-diene and the corresponding tricarbonyliron complex have been synthesized in enantiomerically pure form. Reaction of the complex with trialkylaluminium gave a mono-alkylated product accompanied by racemization.

Graphical abstract: Asymmetric synthesis of C2-symmetric 5,6-bis(benzyloxy)cyclohexa-1,3-diene and a tricarbonyliron complex

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Article information

DOI
https://doi.org/10.1039/B205526K
Article type
Paper
Submitted
10 Jun 2002
Accepted
17 Sep 2002
First published
18 Oct 2002

J. Chem. Soc., Perkin Trans. 1, 2002, 2539-2543

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Asymmetric synthesis of C2-symmetric 5,6-bis(benzyloxy)cyclohexa-1,3-diene and a tricarbonyliron complex

A. Watanabe, T. Kamahori, M. Aso and H. Suemune, J. Chem. Soc., Perkin Trans. 1, 2002, 2539 DOI: 10.1039/B205526K

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