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Issue 45, 2015
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Organocatalytic asymmetric desymmetrization of 4,4-disubstituted cyclohexadienones via an intermolecular Diels–Alder reaction

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Abstract

Asymmetric desymmetrization of 4,4-disubstituted cyclohexadienones via a chiral phosphoric acid-catalyzed enantioselective intermolecular Diels–Alder reaction is developed.

Graphical abstract: Organocatalytic asymmetric desymmetrization of 4,4-disubstituted cyclohexadienones via an intermolecular Diels–Alder reaction

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Article information


Submitted
24 Aug 2015
Accepted
11 Sep 2015
First published
11 Sep 2015

Org. Biomol. Chem., 2015,13, 11039-11045
Article type
Paper

Organocatalytic asymmetric desymmetrization of 4,4-disubstituted cyclohexadienones via an intermolecular Diels–Alder reaction

R. Takagi and T. Nishi, Org. Biomol. Chem., 2015, 13, 11039
DOI: 10.1039/C5OB01760B

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