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Issue 39, 2013
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Catalytic cascade hydroalkoxylation/isomerization/[4 + 2] cycloaddition using enyne alcohols as latent dienes or dienophiles

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Abstract

Enyne alcohols can react as precursors of either dienes or dienophiles with different substrates after hydroxylation and isomerization by gold catalysis. As such, oxa-bridged tricyclo[5.2.2.02,6]undec-8-ene-3,5-dione derivatives have been obtained by the Diels–Alder reaction and tetrahydro-1H-furo[3,4-c]pyran derivatives could be accessed by the hetero-Diels–Alder cycloaddition.

Graphical abstract: Catalytic cascade hydroalkoxylation/isomerization/[4 + 2] cycloaddition using enyne alcohols as latent dienes or dienophiles

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Supplementary files

Article information


Submitted
07 Aug 2013
Accepted
15 Aug 2013
First published
15 Aug 2013

Org. Biomol. Chem., 2013,11, 6707-6712
Article type
Communication

Catalytic cascade hydroalkoxylation/isomerization/[4 + 2] cycloaddition using enyne alcohols as latent dienes or dienophiles

R. Guo, K. Li and L. Gong, Org. Biomol. Chem., 2013, 11, 6707
DOI: 10.1039/C3OB41611A

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