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Issue 21, 2020

K2Ti6O13/carbon core–shell nanorods as a superior anode material for high-rate potassium-ion batteries

Author affiliations

Abstract

Bunches of oriented K2Ti6O13 nanorods coated by a thin carbon layer (4–7 nm) were prepared by combining hydrothermal and heat treatment in sequence. The K2Ti6O13 nanorods possess long- and short-axis crystal orientations of <010> and <001>, respectively, contributing to fast K+ diffusion, and the carbon-coating layer improves the electron conductivity. In addition, the obtained K2Ti6O13/carbon has a high compaction density, which is beneficial for realizing high volumetric specific capacity. When evaluated as a potassium-ion battery anode, the nanorods demonstrated a superior rate capability (122.5, 104.3, 92.3, 78.6 and 65.1 mA h g−1 at current densities of 20, 50, 100, 200 and 500 mA g−1, respectively), a favourable cycle life (118.5 mA h g−1 at 25 mA g−1 for 200 cycles) and high capacity retention.

Graphical abstract: K2Ti6O13/carbon core–shell nanorods as a superior anode material for high-rate potassium-ion batteries

Supplementary files

Article information


Submitted
02 Feb 2020
Accepted
28 Apr 2020
First published
28 Apr 2020

Nanoscale, 2020,12, 11427-11434
Article type
Communication

K2Ti6O13/carbon core–shell nanorods as a superior anode material for high-rate potassium-ion batteries

C. Liu, H. Wang, S. Zhang, M. Han, Y. Cao, S. Liu, Z. Yang, A. Chen and J. Sun, Nanoscale, 2020, 12, 11427 DOI: 10.1039/D0NR00898B

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