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Issue 9, 2016
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The catalyst free synthesis of α-fluorinated aroylacyl imides

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Abstract

The first approach to α-fluorination of aroylacyl imides without a catalyst was accomplished, relying on electrophilic activation through the reaction between a fluoride salt, dimethylsulfoxide and an imide. The synthesis of α-fluorinated aroylacyl imides in good yields was achieved using inexpensive reagents such as NaF and DMSO.

Graphical abstract: The catalyst free synthesis of α-fluorinated aroylacyl imides

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Article information


Submitted
11 Apr 2016
Accepted
11 Jul 2016
First published
12 Jul 2016

New J. Chem., 2016,40, 7604-7611
Article type
Paper

The catalyst free synthesis of α-fluorinated aroylacyl imides

D. Vaithialingam, D. Kumaraguru and S. Ayyanar, New J. Chem., 2016, 40, 7604
DOI: 10.1039/C6NJ01122E

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