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Issue 2, 2009
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Construction of hexanuclear macrocycles by a coupling strategy from polyfunctionalized bis(terpyridines)

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Abstract

The construction of a heteronuclear (Ru4Fe2) hexameric metallomacrocycle with methyl- and carbonyl-functionalized bis(terpyridyl) moieties was achieved by a self-assembly of a dinuclear trimer, which was prepared in high yield viaPd(0) coupling of a bis-iodo functionalized dinuclear complex with a terpyridine possessing an acetylene group.

Graphical abstract: Construction of hexanuclear macrocycles by a coupling strategy from polyfunctionalized bis(terpyridines)

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Publication details

The article was received on 09 Jul 2008, accepted on 26 Sep 2008 and first published on 05 Dec 2008


Article type: Paper
DOI: 10.1039/B811607E
New J. Chem., 2009,33, 345-357

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    Construction of hexanuclear macrocycles by a coupling strategy from polyfunctionalized bis(terpyridines)

    I. Eryazici and G. R. Newkome, New J. Chem., 2009, 33, 345
    DOI: 10.1039/B811607E

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