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Issue 8, 2007
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Synthesis, crystal structure and magnetic properties of a new mixed-valence [Mn4IIIMnII] pentanuclear complex

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Abstract

A novel pentanuclear mixed-valence manganese (II/III) complex [Mn5Na2O2(O2CMe)4(L′)4(DMF)4(H2O)]·3DMF (where H2L′ = 2-hydroxyphenyl-1,3,4-oxadiazole-2(3H)-thione) has been synthesized, structurally and magnetically characterized and presents a butterfly-type spin topology with competing antiferromagnetic interactions.

Graphical abstract: Synthesis, crystal structure and magnetic properties of a new mixed-valence [Mn4IIIMnII] pentanuclear complex

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Article information


Submitted
14 May 2007
Accepted
22 Jun 2007
First published
04 Jul 2007

New J. Chem., 2007,31, 1403-1406
Article type
Letter

Synthesis, crystal structure and magnetic properties of a new mixed-valence [Mn4IIIMnII] pentanuclear complex

C. Beghidja, G. Rogez and R. Welter, New J. Chem., 2007, 31, 1403
DOI: 10.1039/B707170A

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