Issue 8, 2007

Enantiomeric programming in tripodal transition metal scaffolds

Abstract

A new route to the isolation of the enantiopure tris-chelate complex (Δ/Λ)-fac-[Ru(L1)3]2+ (where L1 is 2,2′-bipyridine-5-carboxylic acid) is demonstrated, where the transition metal centre retains the memory of the chirality present in a simple tripodal tether used to control the metal centred geometry.

Graphical abstract: Enantiomeric programming in tripodal transition metal scaffolds

Article information

Article type
Letter
Submitted
13 Mar 2007
Accepted
08 May 2007
First published
25 May 2007

New J. Chem., 2007,31, 1407-1411

Enantiomeric programming in tripodal transition metal scaffolds

N. C. Fletcher, C. Martin and H. J. Abraham, New J. Chem., 2007, 31, 1407 DOI: 10.1039/B703761A

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