Issue 0, 1966

Optically active co-ordination compounds. Part V. The method of less-soluble diastereoisomers and relative configurations

Abstract

The solubilities of diastereoisomeric salts of complexes of cobalt(III) of the type [Co en2XY]n+ with optically active anions are investigated. The resolutions of the ions bisamminebisethylenediaminecobalt(III) and bromoaquobis-ethylenediaminecobalt(III) have been achieved using (+)-antimonyl tartrate salts. The application of the method of less-soluble diastereoisomers in relating optical configurations is discussed, and Jaeger's rule is adopted, that only isomorphous diastereoisomers should be compared; an extension is made to complexes containing optically active ligands. Previous applications are discussed critically. A number of reliable correlations are given, between complexes of cobalt(III) and those of other tervalent metals.

Article information

Article type
Paper

J. Chem. Soc. A, 1966, 802-805

Optically active co-ordination compounds. Part V. The method of less-soluble diastereoisomers and relative configurations

K. Garbett and R. D. Gillard, J. Chem. Soc. A, 1966, 802 DOI: 10.1039/J19660000802

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements