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Issue 4, 2017
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Metal- and oxidant-free S–P(O) bond construction via direct coupling of P(O)H with sulfinic acids

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Abstract

We have developed a simple and convenient method for S–P(O) bond formation between R2P(O)H and sulfinic acids under metal-, oxidant-, and halogen-free conditions. The current method is compatible with a broad range of substituents on various substrates including halogens and heterocyclic moieties. The synthetic potential of this method was further highlighted by the expeditious synthesis of optically active P-chiral phosphorothioates via stereospecific coupling.

Graphical abstract: Metal- and oxidant-free S–P(O) bond construction via direct coupling of P(O)H with sulfinic acids

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Supplementary files

Article information


Submitted
29 Nov 2016
Accepted
12 Dec 2016
First published
13 Dec 2016

Green Chem., 2017,19, 1005-1013
Article type
Paper

Metal- and oxidant-free S–P(O) bond construction via direct coupling of P(O)H with sulfinic acids

Y. Moon, Y. Moon, H. Choi and S. Hong, Green Chem., 2017, 19, 1005
DOI: 10.1039/C6GC03285K

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