Issue 4, 2015
From the journal:

Green Chemistry

High Si/Al ratio HZSM-5 zeolite: an efficient catalyst for the synthesis of polyoxymethylene dimethyl ethers from dimethoxymethane and trioxymethylene†

Jianbing Wu,abc   Huaqing Zhu,a   Zhiwei Wu,a   Zhangfeng Qin,*a   Lai Yan,bd   Baoliang Du,b   Weibin Fana  and  Jianguo Wang*a  

* Corresponding authors

a State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, P.O. Box 165, Taiyuan, Shanxi 030001, PR China
E-mail: qzhf@sxicc.ac.cn, iccjgw@sxicc.ac.cn
Fax: +86-351-4041153
Tel: +86-351-4046092

b Institute of Dalu Coal Chemical Industry, Ordos, Inner Mongolia 010321, PR China

c University of Chinese Academy of Sciences, Beijing 100049, PR China

d Inner Mongolia Supervision Testing and Research Institute for Petroleum Chemical Industry, Hohhot, Inner Mongolia 010021, PR China

Abstract

The catalytic performance of HZSM-5 zeolite in the synthesis of polyoxymethylene dimethyl ethers (PODEn) from dimethoxymethane (DMM) and trioxymethylene (TOM) is closely related to its Si/Al ratio; HZSM-5 with a high Si/Al ratio exhibits high PODE2–8 yield and excellent stability and reusability.

Graphical abstract: High Si/Al ratio HZSM-5 zeolite: an efficient catalyst for the synthesis of polyoxymethylene dimethyl ethers from dimethoxymethane and trioxymethylene

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Article information

DOI
https://doi.org/10.1039/C4GC02510E
Article type
Communication
Submitted
26 Dec 2014
Accepted
17 Feb 2015
First published
19 Feb 2015

Green Chem., 2015,17, 2353-2357

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High Si/Al ratio HZSM-5 zeolite: an efficient catalyst for the synthesis of polyoxymethylene dimethyl ethers from dimethoxymethane and trioxymethylene

J. Wu, H. Zhu, Z. Wu, Z. Qin, L. Yan, B. Du, W. Fan and J. Wang, Green Chem., 2015, 17, 2353 DOI: 10.1039/C4GC02510E

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