Issue 4, 2015
From the journal:

Green Chemistry

Double carbonylation of aryl iodides with amines under an atmospheric pressure of carbon monoxide using sulfur-modified Au-supported palladium†

Nozomi Saito,*ac   Takahisa Taniguchi,a   Naoyuki Hoshiya,‡a   Satoshi Shuto,b   Mitsuhiro Arisawa§*bc  and  Yoshihiro Sato*ac  

* Corresponding authors

a Laboratory of Fine Synthetic Chemistry, Faculty of Pharmaceutical Sciences, Hokkaido University, Sapporo 060-0812, Japan
E-mail: biyo@pharm.hokudai.ac.jp

b Laboratory of Organic Chemistry for Drug Development, Faculty of Pharmaceutical Sciences, Hokkaido University, Sapporo 060-0812, Japan

c ACT-C, Japan Science and Technology Agency (JST), Sapporo, Japan

Abstract

A double carbonylation of aryl iodides with amines proceeded smoothly under an atmospheric pressure of carbon monoxide by using palladium nanoparticles (Pd NPs) leached from a sulfur-modified Au-supported palladium material (SAPd), producing α-ketoamides in good to excellent yields.

Graphical abstract: Double carbonylation of aryl iodides with amines under an atmospheric pressure of carbon monoxide using sulfur-modified Au-supported palladium

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Article information

DOI
https://doi.org/10.1039/C4GC02469A
Article type
Communication
Submitted
18 Dec 2014
Accepted
17 Feb 2015
First published
19 Feb 2015

Green Chem., 2015,17, 2358-2361

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Double carbonylation of aryl iodides with amines under an atmospheric pressure of carbon monoxide using sulfur-modified Au-supported palladium

N. Saito, T. Taniguchi, N. Hoshiya, S. Shuto, M. Arisawa and Y. Sato, Green Chem., 2015, 17, 2358 DOI: 10.1039/C4GC02469A

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