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Issue 3, 2014
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Freedom: a copper-free, oxidant-free and solvent-free palladium catalysed homocoupling reaction

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Abstract

Herein, we describe a copper-free, oxidant-free, solvent-free homocoupling reaction using a palladium catalyst under mechanochemical conditions. We extended the methodology to palladium catalyst on solid support which showed a different reactivity and different product ratios from the non-supported catalyst. We were able to recycle the polymer supported catalyst for 5 cycles.

Graphical abstract: Freedom: a copper-free, oxidant-free and solvent-free palladium catalysed homocoupling reaction

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Supplementary files

Article information


Submitted
04 Sep 2013
Accepted
26 Nov 2013
First published
27 Nov 2013

Green Chem., 2014,16, 1101-1103
Article type
Communication
Author version available

Freedom: a copper-free, oxidant-free and solvent-free palladium catalysed homocoupling reaction

L. Chen, B. E. Lemma, J. S. Rich and J. Mack, Green Chem., 2014, 16, 1101
DOI: 10.1039/C3GC41847B

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