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Issue 11, 2019
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Germylone-bridged bimetallic Ir and Rh complexes

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Abstract

The reactions of germylone 1 with one equivalent of [M(COD)Cl]2 (M = Ir, Rh) afforded the germylone-bridged bimetallic complexes 2 and 3, which have been spectroscopically and structurally characterized. Density functional theory (DFT) studies reveal the relatively strong interactions between the Ge atom and these metals. By the reaction of [Rh(COD)Cl]2 with CO followed by addition of 1, a complex 4 involving a Rh–Ge–Rh–Ge–Rh chain was also synthesized.

Graphical abstract: Germylone-bridged bimetallic Ir and Rh complexes

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Article information


Submitted
11 Jan 2019
Accepted
07 Feb 2019
First published
07 Feb 2019

Dalton Trans., 2019,48, 3555-3559
Article type
Communication

Germylone-bridged bimetallic Ir and Rh complexes

B. Su, K. Ota, Y. Li and R. Kinjo, Dalton Trans., 2019, 48, 3555
DOI: 10.1039/C9DT00145J

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