Barium-promoted hydrothermal stability of monolithic Cu/BEA catalyst for NH3-SCR

Abstract

As a promising candidate for NO_x elimination from the emission of diesel engines, the enhancement effect of Ba on the hydrothermal stability of cordierite supported CuBa/BEA at 600 °C for 48 h was investigated by XRD, NH₃-TPD, H₂-TPR, XPS, EPR, TEM and in situ DRIFTS. Different properties and amounts of active species are significant factors contributing to the enhanced hydrothermal stability of CuBa/BEA-HT. CuBa/BEA-HT has more Cu²⁺/Cu⁺ redox-couples and stronger interactions than Cu/BEA-HT, indicating an excellent redox property of the active species in CuBa/BEA-HT. The better redox property of CuBa/BEA-HT produces more nitrates that easily participate in the NH₃-SCR reaction, which enhances the low-temperature activity. Furthermore, as observed from EPR and H₂-TPR, the appearance of more isolated Cu²⁺ species and fewer CuO species also contribute to the higher hydrothermal stability of CuBa/BEA-HT.