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Issue 28, 2016
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Spatial aromatic fences of metal–organic frameworks for manipulating the electron spin of a fulleropyrrolidine nitroxide radical

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Abstract

The electron spin properties of a fulleropyrrolidine nitroxide radical incarcerated in the pores of MOF-177 and MIL-53 respectively were investigated for the first time. It was found that the spatial confinement effect and intramolecular interactions in these two solid-state spin systems lead to dramatically distinctive spin dynamics.

Graphical abstract: Spatial aromatic fences of metal–organic frameworks for manipulating the electron spin of a fulleropyrrolidine nitroxide radical

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Publication details

The article was received on 03 May 2016, accepted on 20 Jun 2016 and first published on 20 Jun 2016


Article type: Communication
DOI: 10.1039/C6DT01735E
Citation: Dalton Trans., 2016,45, 11272-11276

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    Spatial aromatic fences of metal–organic frameworks for manipulating the electron spin of a fulleropyrrolidine nitroxide radical

    J. Cao, Y. Feng, S. Zhou, X. Sun, T. Wang, C. Wang and H. Li, Dalton Trans., 2016, 45, 11272
    DOI: 10.1039/C6DT01735E

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