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Issue 28, 2016
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Thermal and near-infrared light induced spin crossover in a mononuclear iron(II) complex with a tetrathiafulvalene-fused dipyridophenazine ligand

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Abstract

A mononuclear Fe(II) complex involving a tetrathiafulvalene-based ligand exhibits thermal spin-crossover (around 143 K) with pronounced hysteresis behaviour (48 K). The chromophoric and π-extended ligand allows Near-Infrared (NIR) sensitization for the light-induced excited spin-state trapping (LIESST) with T(LIESST) = 90 K.

Graphical abstract: Thermal and near-infrared light induced spin crossover in a mononuclear iron(ii) complex with a tetrathiafulvalene-fused dipyridophenazine ligand

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Publication details

The article was received on 07 Mar 2016, accepted on 22 Jun 2016 and first published on 24 Jun 2016


Article type: Communication
DOI: 10.1039/C6DT00920D
Citation: Dalton Trans., 2016,45, 11267-11271
  • Open access: Creative Commons BY license
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    Thermal and near-infrared light induced spin crossover in a mononuclear iron(II) complex with a tetrathiafulvalene-fused dipyridophenazine ligand

    F. Pointillart, X. Liu, M. Kepenekian, B. Le Guennic, S. Golhen, V. Dorcet, T. Roisnel, O. Cador, Z. You, J. Hauser, S. Decurtins, L. Ouahab and S.-X. Liu, Dalton Trans., 2016, 45, 11267
    DOI: 10.1039/C6DT00920D

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