Issue 20, 2016
From the journal:

Dalton Transactions

Does [TcF(CO)5] exist? The crystal and molecular structure of [Tc(CO)3(OH)0.49F0.51]4·[Tc(CO)5(BF4)]†

E. S. Stepanova,a   V. V. Gurzhiy,b   M. Yu. Tyupina,a   A. E. Miroslavov,*a   G. V. Sidorenkoa  and  A. A. Lumpova  

* Corresponding authors

a Khlopin Radium Institute, 2-i Murinskii pr. 28, St. Petersburg, 194021 Russia
E-mail: amiroslav@mail.ru

b Department of Crystallography, St. Petersburg State University, University emb. 7/9, St. Petersburg, 199034 Russia

Abstract

Technetium pentacarbonyl fluoride [TcF(CO)5] was prepared for the first time by reaction of [TcI(CO)5] with solid AgF in a dichloromethane solution at −23 °C. Low temperature crystallization of the resulting compound in a glass vial yielded an unusual complex [Tc(CO)3(OH)0.49F0.51]4·[Tc(CO)5(BF4)] characterized by single crystal XRD.

Graphical abstract: Does [TcF(CO)5] exist? The crystal and molecular structure of [Tc(CO)3(OH)0.49F0.51]4·[Tc(CO)5(BF4)]

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Article information

DOI
https://doi.org/10.1039/C6DT00958A
Article type
Paper
Submitted
10 Mar 2016
Accepted
08 Apr 2016
First published
08 Apr 2016
This article is Open Access
Creative Commons BY license

Dalton Trans., 2016,45, 8428-8432

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Does [TcF(CO)5] exist? The crystal and molecular structure of [Tc(CO)3(OH)0.49F0.51]4·[Tc(CO)5(BF4)]

E. S. Stepanova, V. V. Gurzhiy, M. Yu. Tyupina, A. E. Miroslavov, G. V. Sidorenko and A. A. Lumpov, Dalton Trans., 2016, 45, 8428 DOI: 10.1039/C6DT00958A

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