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Issue 31, 2014
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Mechanochemical synthesis of crystalline and amorphous digold(i) helicates exhibiting anion- and phase-switchable luminescence properties

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Abstract

For the first time, mechanochemical synthesis has been used for the preparation of crystalline and amorphous dinuclear gold(I) helicates, [Au2L2](X)2 (L = xantphos; X = CF3SO3, SCN, BF4 and PF6), that show anion- and phase-switchable luminescence properties. This solid-state approach provides strategies for developing switchable luminescent materials.

Graphical abstract: Mechanochemical synthesis of crystalline and amorphous digold(i) helicates exhibiting anion- and phase-switchable luminescence properties

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Supplementary files

Article information


Submitted
25 Apr 2014
Accepted
11 Jun 2014
First published
11 Jun 2014

Dalton Trans., 2014,43, 11807-11810
Article type
Communication
Author version available

Mechanochemical synthesis of crystalline and amorphous digold(I) helicates exhibiting anion- and phase-switchable luminescence properties

C. Jobbágy, M. Molnár, P. Baranyai and A. Deák, Dalton Trans., 2014, 43, 11807
DOI: 10.1039/C4DT01214C

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