Issue 48, 2013
From the journal:

Dalton Transactions

An emitting Hofmann-type compound: evidence for interlayer aurophilic interactions†

Takafumi Kitazawa,*a   Kei Hiruma,a   Hisako Sato,b   Kenji Tamurac  and  Akihiko Yamagishia  

* Corresponding authors

a Department of Chemistry, Toho University, Funabashi, Chiba 274-8510, Japan
E-mail: kitazawa@chem.sci.toho-u.ac.jp
Fax: +81-47-472-5081
Tel: +81-47-472-5081

b Department of Chemistry, Graduate School of Science and Engineering, Ehime University, Matsuyama 790-8577, Japan

c NIMS, Namiki, Tsukuba 305-0044, Japan

Abstract

A newly synthesized Hofmann-type bimetallic coordination polymer, [CdII(3-methylpyridine)2][Au(CN)2]2, was luminescent with emission peaks at 400 nm, 440 nm, 490 nm and 550 nm (shoulder) under irradiation at 360 nm, whose multiple peak character in the emission spectrum was rationalized in terms of the vibrational structures in the interactions between the Au atoms in adjacent layers.

Graphical abstract: An emitting Hofmann-type compound: evidence for interlayer aurophilic interactions

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Article information

DOI
https://doi.org/10.1039/C3DT52303A
Article type
Communication
Submitted
22 Aug 2013
Accepted
06 Oct 2013
First published
08 Oct 2013

Dalton Trans., 2013,42, 16680-16682

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An emitting Hofmann-type compound: evidence for interlayer aurophilic interactions

T. Kitazawa, K. Hiruma, H. Sato, K. Tamura and A. Yamagishi, Dalton Trans., 2013, 42, 16680 DOI: 10.1039/C3DT52303A

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