Hexa-substituted polyoxometalates made of trivacant Dawson {P2W15} fragments and {Ni6} clusters under hydrothermal conditions

Yong-Chao Liu; Chun-Hua Fu; Shou-Tian Zheng; Jun-Wei Zhao; Guo-Yu Yang

doi:10.1039/C3DT51786A

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Hexa-substituted polyoxometalates made of trivacant Dawson {P₂W₁₅} fragments and {Ni₆} clusters under hydrothermal conditions†

Yong-Chao Liu,^a Chun-Hua Fu,^a Shou-Tian Zheng,^a Jun-Wei Zhao*^b and Guo-Yu Yang*^a

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* Corresponding authors

^a Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
E-mail: ygy@fjirsm.ac.cn
Fax: (+86) 591-8371-0051

^b Henan Key Laboratory of Polyoxometalate Chemistry, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, Henan 475004, P. R. China
E-mail: zhaojunwei@henu.edu.cn

Abstract

Three novel polyoxometalates (POMs) containing [Ni₆(μ₃-OH)₃]⁹⁻ and [P₂W₁₅O₅₆]¹²⁻ units were first made, showing the first hexa-nuclearity transition-metal substituted POMs (TMSPs) based on monomeric lacunary Dawson fragments, which further indicates that the hydrothermal technique can offer an effective way for making new TMSPs through lacunary POM fragments incorporated with high-nuclear TM clusters.

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Article information

DOI: https://doi.org/10.1039/C3DT51786A
Article type: Communication
Submitted: 03 Jul 2013
Accepted: 07 Oct 2013
First published: 08 Oct 2013

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Dalton Trans., 2013,42, 16676-16679

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Hexa-substituted polyoxometalates made of trivacant Dawson {P₂W₁₅} fragments and {Ni₆} clusters under hydrothermal conditions

Y. Liu, C. Fu, S. Zheng, J. Zhao and G. Yang, Dalton Trans., 2013, 42, 16676 DOI: 10.1039/C3DT51786A

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Dalton Transactions