Issue 5, 2010
From the journal:

Dalton Transactions

Synthesis and complexation of heptafluoroisopropyldiphenylphosphine†‡

Lesley C. Lewis-Alleyne,a   Makeba B. Murphy-Jolly,a   Xavier F. Le Goffb  and  Andrew J. M. Caffyn*ac  

* Corresponding authors

a Department of Chemistry, The University of the West Indies, St. Augustine, Trinidad & Tobago

b Laboratorie “Hétéroéléments et Coordination”, Ecole Polytechnique, CNRS UMR 7653, Cédex, France

c School of Biology, Chemistry & Health Science, Manchester Metropolitan University, John Dalton Building, Chester St., Manchester, UK
E-mail: a.caffyn@mmu.ac.uk
Tel: +44(0)161 2471443

Abstract

We report a one-step synthesis of the phosphine, PPh2iC3F7 from commercially available precursors. The stereoelectronic properties of the phosphine were probed by coordination to transition metals. Mo(CO)5PPh2iC3F7 was synthesised and the synthesis and structure of trans-PtCl2(PPh2iC3F7)2 are described. PPh2iC3F7 was found to be a bulky electron-withdrawing ligand.

Graphical abstract: Synthesis and complexation of heptafluoroisopropyldiphenylphosphine

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Article information

DOI
https://doi.org/10.1039/B918348E
Article type
Communication
Submitted
07 Sep 2009
Accepted
26 Oct 2009
First published
11 Nov 2009

Dalton Trans., 2010,39, 1198-1200

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Synthesis and complexation of heptafluoroisopropyldiphenylphosphine

L. C. Lewis-Alleyne, M. B. Murphy-Jolly, X. F. Le Goff and A. J. M. Caffyn, Dalton Trans., 2010, 39, 1198 DOI: 10.1039/B918348E

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