Issue 26, 2009
From the journal:

Dalton Transactions

The [1,2,3]Triazolo[1,5-a]pyridine ring: A sensitive sensor for the electronic profile of phosphorus substituents†

Rafael Ballesteros-Garrido,a   Laurence Bonnafoux,a   Frédéric R. Leroux,*a   Belén Abarca*b  and  Françoise Colobert*a  

* Corresponding authors

a CNRS and University of Strasbourg (ECPM), UMR 7509, 25 rue Becquerel, Strasbourg, France
E-mail: frederic.leroux@unistra.fr, francoise.colobert@unistra.fr
Fax: +33 (0)3-90-24-27-42

b Departament de Quimica Orgànica, Facultad de Farmacia, Universidad de Valencia, Avda. Vicente Andrés Estellés s/n, Valencia, Burjassot, Spain
E-mail: Belen.Abarca@uv.es

Abstract

The unique nature of the [1,2,3]triazolo[1,5-a]pyridine reveals without any external perturbation the electronic contribution of various substituents to the phosphorus atom in phosphines, based on the equilibrium of two possible ring-chain isomers.

Graphical abstract: The [1,2,3]Triazolo[1,5-a]pyridine ring: A sensitive sensor for the electronic profile of phosphorus substituents

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Article information

DOI
https://doi.org/10.1039/B906034K
Article type
Communication
Submitted
27 Mar 2009
Accepted
24 Apr 2009
First published
08 May 2009

Dalton Trans., 2009, 5068-5070

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The [1,2,3]Triazolo[1,5-a]pyridine ring: A sensitive sensor for the electronic profile of phosphorus substituents

R. Ballesteros-Garrido, L. Bonnafoux, F. R. Leroux, B. Abarca and F. Colobert, Dalton Trans., 2009, 5068 DOI: 10.1039/B906034K

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