Polynuclear titanocene complexes with antimony ligands: [(Cp2Ti)2(SbR2)2] (R = Et), [(Cp2Ti)3(SbR)3Sb] [R = 2-(Me2NCH2)C6H4] and [(Cp2Ti)5(SbR)2Sb7] (R = Me3SiCH2)

Hans J. Breunig; Enno Lork; Ovidiu Moldovan; Ciprian I. Raţ; Uwe Rosenthal; Cristian Silvestru

doi:10.1039/B904846D

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Polynuclear titanocene complexes with antimony ligands: [(Cp₂Ti)₂(SbR₂)₂] (R = Et), [(Cp₂Ti)₃(SbR)₃Sb] [R = 2-(Me₂NCH₂)C₆H₄] and [(Cp₂Ti)₅(SbR)₂Sb₇] (R = Me₃SiCH₂)†

Hans J. Breunig,*^a Enno Lork,^a Ovidiu Moldovan,^a Ciprian I. Raţ,^b Uwe Rosenthal^c and Cristian Silvestru^b

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* Corresponding authors

^a Institut für Anorganische und Physikalische Chemie, Universität Bremen, Postfach 330 440, Bremen, Germany
E-mail: hbreunig@uni-bremen.de
Fax: +49 421 218 4042
Tel: +49 421 218 2266

^b Facultatea de Chimie si Inginerie Chimica Universitatea Babes-Bolyai Arany Janos 11, Cluj-Napoca, Romania

^c Leibniz-Institut für Katalyse e.V., Universität Rostock, Albert-Einstein-Strasse 29a, Rostock, Germany

Abstract

The formation and crystal structure of [(Cp₂Ti)₂(SbR₂)₂] (1, R = Et), [(Cp₂Ti)₃(SbR)₃Sb] [2, R = 2-(Me₂NCH₂)C₆H₄], and [(Cp₂Ti)₅(SbR)₂Sb₇] (3, R = Me₃SiCH₂) is reported.

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Article information

DOI: https://doi.org/10.1039/B904846D
Article type: Communication
Submitted: 10 Mar 2009
Accepted: 01 May 2009
First published: 13 May 2009

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Dalton Trans., 2009, 5065-5067

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Polynuclear titanocene complexes with antimony ligands: [(Cp₂Ti)₂(SbR₂)₂] (R = Et), [(Cp₂Ti)₃(SbR)₃Sb] [R = 2-(Me₂NCH₂)C₆H₄] and [(Cp₂Ti)₅(SbR)₂Sb₇] (R = Me₃SiCH₂)

H. J. Breunig, E. Lork, O. Moldovan, C. I. Raţ, U. Rosenthal and C. Silvestru, Dalton Trans., 2009, 5065 DOI: 10.1039/B904846D

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Dalton Transactions