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Issue 26, 2009
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Polynuclear titanocene complexes with antimony ligands: [(Cp2Ti)2(SbR2)2] (R = Et), [(Cp2Ti)3(SbR)3Sb] [R = 2-(Me2NCH2)C6H4] and [(Cp2Ti)5(SbR)2Sb7] (R = Me3SiCH2)

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Abstract

The formation and crystal structure of [(Cp2Ti)2(SbR2)2] (1, R = Et), [(Cp2Ti)3(SbR)3Sb] [2, R = 2-(Me2NCH2)C6H4], and [(Cp2Ti)5(SbR)2Sb7] (3, R = Me3SiCH2) is reported.

Graphical abstract: Polynuclear titanocene complexes with antimony ligands: [(Cp2Ti)2(SbR2)2] (R = Et), [(Cp2Ti)3(SbR)3Sb] [R = 2-(Me2NCH2)C6H4] and [(Cp2Ti)5(SbR)2Sb7] (R = Me3SiCH2)

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Article information


Submitted
10 Mar 2009
Accepted
01 May 2009
First published
13 May 2009

Dalton Trans., 2009, 5065-5067
Article type
Communication

Polynuclear titanocene complexes with antimony ligands: [(Cp2Ti)2(SbR2)2] (R = Et), [(Cp2Ti)3(SbR)3Sb] [R = 2-(Me2NCH2)C6H4] and [(Cp2Ti)5(SbR)2Sb7] (R = Me3SiCH2)

H. J. Breunig, E. Lork, O. Moldovan, C. I. Raţ, U. Rosenthal and C. Silvestru, Dalton Trans., 2009, 5065
DOI: 10.1039/B904846D

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