Issue 28, 2008
From the journal:

Dalton Transactions

Assembly of a two-dimensional oxalate-bridged heterometallic CoII3CrIII2 coordination polymer†

Hui-Zhong Kou,*ab   Jun Taoc  and  Osamu Sato*a  

* Corresponding authors

a Institute for Materials Chemistry and Engineering, Kyushu University, 6-1 Kasuga-koen, Kasuga, Fukuoka, Japan
E-mail: sato@chem.kyushu-u.ac.jp
Fax: +81-92-5837787

b Department of Chemistry, Tsinghua University, Beijing, China
E-mail: kouhz@mail.tsinghua.edu.cn

c Department of Chemistry, State Key Laboratory for Physical Chemistry of Solid Surfaces, Xiamen University, Xiamen, China

Abstract

Reaction of CoCl2·4H2O with Ag3[Cr(ox)3] (3 : 2 mol/mol) in methanol gives rise to an oxalate-bridged complex [Co(MeOH)2]3[Cr(ox)3]2·6MeOH that consists of a rare cloverleaf-like layered structure (12,3-net). Ferromagnetic coupling is operative between the adjacent metal ions through the oxalate bridges.

Graphical abstract: Assembly of a two-dimensional oxalate-bridged heterometallic CoII3CrIII2 coordination polymer

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Article information

DOI
https://doi.org/10.1039/B800659H
Article type
Communication
Submitted
14 Jan 2008
Accepted
02 May 2008
First published
28 May 2008

Dalton Trans., 2008, 3652-3654

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Assembly of a two-dimensional oxalate-bridged heterometallic CoII3CrIII2 coordination polymer

H. Kou, J. Tao and O. Sato, Dalton Trans., 2008, 3652 DOI: 10.1039/B800659H

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