Issue 20, 2002
From the journal:

Journal of the Chemical Society, Dalton Transactions

Novel three-dimensional framework based on Ba9 cores involving unprecedented μ5-η3:η3-acetate anions

Guo Dong,a   Zhang Bing-guang,ab   Duan Chun-ying,*a   Pang Ke-lianga  and  Meng Qing-jin*a  

* Corresponding authors

a Coordination Chemistry Institute, The State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, 210093, P. R. China
E-mail: duancy@nju.edu.cn

b Department of Chemistry, Wuhan University, Wuhan, P. R. China

Abstract

A three-dimensional framework based on a body-centered Ba9 cluster has been assembled, in which the bridging acetate anions show novel μ5-η3:η3-, μ4-η2:η2- and μ3-η2:η2-bridging coordination modes, while the perchlorate anions display an unusual μ4-η1:η1:η2-coordination mode.

Graphical abstract: Novel three-dimensional framework based on Ba9 cores involving unprecedented μ5-η3:η3-acetate anions

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Article information

DOI
https://doi.org/10.1039/B207889A
Article type
Communication
Submitted
12 Aug 2002
Accepted
11 Sep 2002
First published
23 Sep 2002

J. Chem. Soc., Dalton Trans., 2002, 3783-3784

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Novel three-dimensional framework based on Ba9 cores involving unprecedented μ5-η3:η3-acetate anions

G. Dong, Z. Bing-guang, D. Chun-ying, P. Ke-liang and M. Qing-jin, J. Chem. Soc., Dalton Trans., 2002, 3783 DOI: 10.1039/B207889A

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