Issue 20, 2002

A novel route to chalcogenides of heavy pnicogens: synthesis and X-ray structure of {(THF)3Li2[PhAs(Se)(NBut)2]}

Abstract

The rapid reaction of Li2[PhAs(NBut)2] with elemental selenium in THF at 23 °C produces {(THF)3Li2[PhAs(Se)(NBut)2]}, which contains a formal As[double bond, length as m-dash]Se double bond.

Graphical abstract: A novel route to chalcogenides of heavy pnicogens: synthesis and X-ray structure of {(THF)3Li2[PhAs(Se)(NBut)2]}

Supplementary files

Article information

Article type
Communication
Submitted
25 Jul 2002
Accepted
12 Sep 2002
First published
23 Sep 2002

J. Chem. Soc., Dalton Trans., 2002, 3785-3786

A novel route to chalcogenides of heavy pnicogens: synthesis and X-ray structure of {(THF)3Li2[PhAs(Se)(NBut)2]}

G. G. Briand, T. Chivers and M. Parvez, J. Chem. Soc., Dalton Trans., 2002, 3785 DOI: 10.1039/B207302A

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