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Issue 5, 2000

Synthesis and crystal structure of a new strontium nitridomolybdate oxide, Sr4[MoN4]O

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Abstract

The new ternary nitride oxide Sr4[MoN4]O was synthesised by the reaction of strontium nitride with molybdenum nitride under a low partial pressure of oxygen in a sealed stainless steel crucible. Structure determination from single crystal X-ray data showed the structure to be monoclinic in the space group P21/m (no. 11). The crystal morphology and strontium/molybdenum ratios were investigated using scanning electron microscopy and energy dispersive analysis by X-rays. The structure contains isolated [MoN4]6− tetrahedra. Oxygen is ordered in the anion sublattice and is found only in the co-ordination sphere of the alkaline earth metal.

Supplementary files

Article information


Submitted
29 Sep 1999
Accepted
26 Jan 2000
First published
14 Feb 2000

J. Chem. Soc., Dalton Trans., 2000, 633-638
Article type
Paper

Synthesis and crystal structure of a new strontium nitridomolybdate oxide, Sr4[MoN4]O

P. M. O’Meara, M. G. Barker, A. J. Blake, P. A. Cooke and D. H. Gregory, J. Chem. Soc., Dalton Trans., 2000, 633 DOI: 10.1039/A907843F

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