Issue 5, 2000
From the journal:

Journal of the Chemical Society, Dalton Transactions

Syntheses and structures of novel heterobimetallic Cu(II)–Au(I) complexes Cu(cyclen)[Au(CN)2]2 and Cu(pyz)[Au(CN)2]2

Wai-Fun Yeung,a   Wing-Tak Wong,b   Jing-Lin Zuoc  and  Tai-Chu Lau*a  

* Corresponding authors

a Department of Biology and Chemistry, City University of Hong Kong, Tat Chee Avenue, Hong Kong, P.R. China
E-mail: bhtclau@cityu.edu.hk

b Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong, P.R. China

c Coordination Chemistry Institute and the State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, P.R. China

Abstract

Two novel cyano CuII–AuI bimetallic complexes, Cu(cyclen)[Au(CN)2]21 (cyclen = 1,4,7,10-tetraazacyclododecane) and Cu(pyz)[Au(CN)2]22 (pyz = pyrazine) were prepared; 1 has a dimeric structure arising from AuI ⋯ AuI interactions, while 2 consists of linear pyrazine-bridged copper chains intercalated to produce a 2-D pleated sheet structure.

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Article information

DOI
https://doi.org/10.1039/A910350N
Article type
Communication
Submitted
24 Dec 1999
Accepted
02 Feb 2000
First published
28 Feb 2000

J. Chem. Soc., Dalton Trans., 2000, 629-631

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Syntheses and structures of novel heterobimetallic Cu(II)–Au(I) complexes Cu(cyclen)[Au(CN)2]2 and Cu(pyz)[Au(CN)2]2

W. Yeung, W. Wong, J. Zuo and T. Lau, J. Chem. Soc., Dalton Trans., 2000, 629 DOI: 10.1039/A910350N

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