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Issue 10, 2019
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Tailoring the morphology of Ni–Pt nanocatalysts through the variation of oleylamine and oleic acid: a study on oxygen reduction from synthesis to fuel cell application

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Abstract

Recent research has focused on the control of the geometric shape of nanoparticles (NPs) to improve their catalytic activity for the oxygen reduction reaction (ORR) in PEM fuel cells. This work studies the effect of the Oam : Oac ratio on the size, morphology, and catalytic activity of several carbon-supported Ni–Pt nanomaterials. Electrochemical tests using ring-disk electrode techniques were used to evaluate the catalytic activity and peroxide formation toward the ORR in acid media. STEM, SEM, EDS, and XRD were performed to study the physical properties of the nanocatalysts synthesized. UV-vis and FTIR spectroscopy were used to characterize the metal–ligand complexes formed during the synthesis. Additionally, accelerated electrochemical degradation testing was undertaken to evaluate the stability of the catalysts. The best nanomaterial in terms of high catalytic activity and stability was chosen and applied as the cathode for fuel cell evaluations. Experimental results revealed that the exclusive use of Oam during the synthesis resulted in polyhedral nanoparticles with the best catalytic activity toward the ORR. On the other hand, an increase in Oac content caused a decrease in Ni content through the formation of a Ni2+:carboxylate complex which promotes nanoparticles smaller in size, variations in their morphology, and a decrease in their catalytic activity.

Graphical abstract: Tailoring the morphology of Ni–Pt nanocatalysts through the variation of oleylamine and oleic acid: a study on oxygen reduction from synthesis to fuel cell application

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Publication details

The article was received on 01 Mar 2019, accepted on 08 Apr 2019 and first published on 09 Apr 2019


Article type: Paper
DOI: 10.1039/C9CY00419J
Catal. Sci. Technol., 2019,9, 2630-2650

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    Tailoring the morphology of Ni–Pt nanocatalysts through the variation of oleylamine and oleic acid: a study on oxygen reduction from synthesis to fuel cell application

    J. L. Reyes-Rodríguez, A. Velázquez-Osorio, D. Bahena-Uribe, A. B. Soto-Guzmán, M. A. Leyva, A. Rodríguez-Castellanos, S. Citalán-Cigarroa and O. Solorza-Feria, Catal. Sci. Technol., 2019, 9, 2630
    DOI: 10.1039/C9CY00419J

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