A highly-connected metal–organic framework based on [Co2(μ2-OH2)] units and mononuclear Co centers with high gas uptake capacity

Yao Kang; Fei Wang

doi:10.1039/C3CE42361A

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A highly-connected metal–organic framework based on [Co₂(μ₂-OH₂)] units and mononuclear Co centers with high gas uptake capacity†

Yao Kang^a and Fei Wang*^a

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* Corresponding authors

^a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fujian 350002, Fuzhou, PR China
E-mail: wangfei04@fjirsm.ac.cn

Abstract

A porous 3D framework based on [Co₂(μ₂-OH₂)] clusters and mononuclear Co centers, is presented. The [Co₂(μ₂-OH₂)] units act as 7-connected and 8-connected nodes, respectively. The desolvated form of 1 shows high CO₂ and H₂ adsorption.

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Article information

DOI: https://doi.org/10.1039/C3CE42361A
Article type: Communication
Submitted: 20 Nov 2013
Accepted: 21 Feb 2014
First published: 21 Feb 2014

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CrystEngComm, 2014,16, 4088-4090

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A highly-connected metal–organic framework based on [Co₂(μ₂-OH₂)] units and mononuclear Co centers with high gas uptake capacity

Y. Kang and F. Wang, CrystEngComm, 2014, 16, 4088 DOI: 10.1039/C3CE42361A

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