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Issue 20, 2014
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Pressure-induced isostructural phase transition of a metal–organic framework Co2(4,4′-bpy)3(NO3)4·xH2O

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Abstract

Based on the 4,4′-bipyridine organic linker, metal–organic frameworks of Co2(4,4′-bpy)3(NO3)4·xH2O (CB-MOF) have been prepared. The pressure-dependent structure evolution of CB-MOF has been investigated up to 11 GPa. An isostructural phase transition was observed at about 6 GPa followed by negative compressibility along the b axis.

Graphical abstract: Pressure-induced isostructural phase transition of a metal–organic framework Co2(4,4′-bpy)3(NO3)4·xH2O

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Publication details

The article was received on 23 Dec 2013, accepted on 18 Feb 2014 and first published on 19 Feb 2014


Article type: Communication
DOI: 10.1039/C3CE42607F
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Citation: CrystEngComm, 2014,16, 4084-4087
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    Pressure-induced isostructural phase transition of a metal–organic framework Co2(4,4′-bpy)3(NO3)4·xH2O

    M. Zhou, K. Wang, Z. Men, C. Sun, Z. Li, B. Liu, G. Zou and B. Zou, CrystEngComm, 2014, 16, 4084
    DOI: 10.1039/C3CE42607F

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