Issue 23, 2012
From the journal:

CrystEngComm

Carboxylic acid-derived oxacalix[2]arene[2]pyrazine self-assembles into unprecedented diamondoid networks†

Xiao-Yan Li,a   Ke-Ying Yu,a   Xiao-Li Zhao,b   Ming-Liang Ma,*a   Fang Guo,c   Xian-Qiang Mi,c   Biao Jiang*c  and  Ke Wen*ac  

* Corresponding authors

a Shanghai Engineering Research Center of Molecular Therapeutics and New Drug Development, East China Normal University, Shanghai 200062, China
E-mail: mlma@brain.ecnu.edu.cn, kwen@brain.ecnu.edu.cn
Fax: +8621-6260-1953
Tel: +8621-6223-7102

b Shanghai Key Laboratory of Green Chemistry and Chemical Processes and Department of Chemistry, East China Normal University, Shanghai 200062, China

c Center for Nanomedicine, Shanghai Advanced Research Institute, Chinese Academy of Science, Shanghai 201203, China
E-mail: jiangb@sari.ac.cn, wenk@sari.ac.cn
Fax: +86 21-5080-7562
Tel: +86 21-5080-8085

Abstract

A 1,3-alternate conformational oxacalix[2]arene[2]pyrazine, 1, made up of two tetrahedrally oriented –COOH functions and two upper rim pyrazinyl nitrogen atoms, self-assembles into an unprecedented six-fold interpenetrated diamondoid network via intermolecular hydrogen bond interactions. Disordered guest molecules could be included in the hydrophobic channels presented in the supramolecular aggregates.

Graphical abstract: Carboxylic acid-derived oxacalix[2]arene[2]pyrazine self-assembles into unprecedented diamondoid networks

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Article information

DOI
https://doi.org/10.1039/C2CE25315A
Article type
Communication
Submitted
05 Mar 2012
Accepted
30 Aug 2012
First published
31 Aug 2012

CrystEngComm, 2012,14, 7869-7871

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Carboxylic acid-derived oxacalix[2]arene[2]pyrazine self-assembles into unprecedented diamondoid networks

X. Li, K. Yu, X. Zhao, M. Ma, F. Guo, X. Mi, B. Jiang and K. Wen, CrystEngComm, 2012, 14, 7869 DOI: 10.1039/C2CE25315A

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