Issue 23, 2012
From the journal:

CrystEngComm

Three guest-dependent nitrate–water aggregations encapsulated in silver(i)–bipyridine supramolecular frameworks†

Di Sun,*a   Fu-Jing Liu,b   Rong-Bin Huangb  and  Lan-Sun Zhengb  

* Corresponding authors

a Key Lab of Colloid and Interface Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, Shandong University, Jinan, Shandong, China
E-mail: dsun@sdu.edu.cn
Fax: +86-531-88364218

b State Key Laboratory of Physical Chemistry of Solid Surface, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005, China

Abstract

Three well-isolated hydrogen-bonded nitrate–water aggregations, namely, [(NO3)4(H2O)6]n, [(NO3)2(H2O)2]n and [(NO3)2(H2O)] are unmasked in three similar silver(I)–bipyridine supramolecular frameworks, formulated as [Ag4(bipy)4·o-abn·4NO3·6H2O]n (1), [Ag3(bipy)3·m-abn·3NO3·2H2O]n (2) and [Ag2(bipy)2·p-abn·2NO3·H2O]n (3) (bipy = bipyridine, abn = aminobenzonitrile). Although the hosts of the three supramolecular frameworks are similar and comprised of common silver(I)–bipyridine chain structures, isomeric abn (aminobenzonitrile) guest molecules create the different micro-environments for accommodating the diverse nitrate–water aggregations. Moreover, the thermal stabilities and luminescent properties of 1–3 are discussed.

Graphical abstract: Three guest-dependent nitrate–water aggregations encapsulated in silver(i)–bipyridine supramolecular frameworks

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C2CE26161H
Article type
Communication
Submitted
19 Jul 2012
Accepted
13 Sep 2012
First published
14 Sep 2012

CrystEngComm, 2012,14, 7872-7876

Permissions

Request permissions

Three guest-dependent nitrate–water aggregations encapsulated in silver(I)–bipyridine supramolecular frameworks

D. Sun, F. Liu, R. Huang and L. Zheng, CrystEngComm, 2012, 14, 7872 DOI: 10.1039/C2CE26161H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements