Issue 12, 2011
From the journal:

CrystEngComm

Buffering additive effect in the formation of metal–carboxylate frameworks with slightly different linear M3(RCOO)6 clusters†

Xiao-Feng Wang,ab   Yue-Biao Zhang,a   Wei-Xiong Zhang,a   Wei Xue,a   Hao-Long Zhoua  and  Xiao-Ming Chen*a  

* Corresponding authors

a MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, State Key Laboratory of Optoelectronic Materials, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou, China
E-mail: cxm@mail.sysu.edu.cn

b School of Chemistry and Chemical Engineering, University of South China, Hengyang, China

Abstract

By treating M(NO3)2 or MCl2 (M = Mn, Fe, Co and Ni) with 2,6-naphthalene dicarboxylic acid (ndcH2), a series of metal–carboxylate frameworks have been solvothermally synthesized under the same route with different buffering anions, which feature two kinds of frameworks based on slightly different linear M3(OOCR)6 secondary building units: [M3(ndc)3(DMF)4]n (M = MnII, FeII and CoII) or [M3(ndc)3(DMF)2(Me2NH)2]n (M = CoII and NiII). Consequently, the two cobalt compounds exhibit different magnetic behaviours.

Graphical abstract: Buffering additive effect in the formation of metal–carboxylate frameworks with slightly different linear M3(RCOO)6 clusters

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Article information

DOI
https://doi.org/10.1039/C1CE05190C
Article type
Paper
Submitted
10 Feb 2011
Accepted
30 Mar 2011
First published
09 May 2011

CrystEngComm, 2011,13, 4196-4201

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Buffering additive effect in the formation of metal–carboxylate frameworks with slightly different linear M3(RCOO)6 clusters

X. Wang, Y. Zhang, W. Zhang, W. Xue, H. Zhou and X. Chen, CrystEngComm, 2011, 13, 4196 DOI: 10.1039/C1CE05190C

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