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Issue 56, 2020
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Rhodium(iii)-catalyzed diamidation of olefins via amidorhodation and further amidation

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Abstract

Rh(III)-catalyzed synthesis of vicinal diamides has been realized via elaboration of an authenticated Rh–C(sp3) species generated via initial intramolecular amidorhodation of olefins. The second amidation was achieved using both electrophilic and nucleophilic amidating reagents. The reactions proceeded under mild conditions with good yield, broad substrate scope, and excellent functional-group tolerance.

Graphical abstract: Rhodium(iii)-catalyzed diamidation of olefins via amidorhodation and further amidation

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Article information


Submitted
06 Feb 2020
Accepted
25 Jun 2020
First published
26 Jun 2020

Chem. Commun., 2020,56, 7809-7812
Article type
Communication

Rhodium(III)-catalyzed diamidation of olefins via amidorhodation and further amidation

J. Wang, G. Zheng and X. Li, Chem. Commun., 2020, 56, 7809
DOI: 10.1039/D0CC00952K

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