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Issue 55, 2019
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π Complexes of P^P and P^N chelated gold(i)

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Abstract

Tricoordinate gold(I) π-complexes containing P-based chelating ligands (P^P and P^N) were prepared. The structure of the gold(I) styrene complexes has been analysed in detail based on NMR and XRD data. The P^N complex is a competent catalyst for indole alkylation. The reaction proceeds with complete C3 and Markovnikov selectivity.

Graphical abstract: π Complexes of P^P and P^N chelated gold(i)

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Article information


Submitted
03 Jun 2019
Accepted
13 Jun 2019
First published
13 Jun 2019

Chem. Commun., 2019,55, 7974-7977
Article type
Communication

π Complexes of P^P and P^N chelated gold(I)

M. Navarro, A. Toledo, M. Joost, A. Amgoune, S. Mallet-Ladeira and D. Bourissou, Chem. Commun., 2019, 55, 7974
DOI: 10.1039/C9CC04266K

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