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Issue 23, 2019
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Mn2CoReO6: a robust multisublattice antiferromagnetic perovskite with small A-site cations

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Abstract

Mn2CoReO6, the fourth known magnetic transition-metal-only double perovskite oxide (space group P21/n) was synthesized at high pressure and temperature (8 GPa, 1350 °C). Large structural distortions are induced by the small A-site Mn2+ cations. Mn2CoReO6 exhibits complex magnetic properties with a robust antiferromagnetic order (TN = 94 K) involving all cation sublattices.

Graphical abstract: Mn2CoReO6: a robust multisublattice antiferromagnetic perovskite with small A-site cations

  • This article is part of the themed collection: Perovskites
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Supplementary files

Article information


Submitted
02 Jan 2019
Accepted
19 Feb 2019
First published
19 Feb 2019

Chem. Commun., 2019,55, 3331-3334
Article type
Communication
Author version available

Mn2CoReO6: a robust multisublattice antiferromagnetic perovskite with small A-site cations

C. E. Frank, E. E. McCabe, F. Orlandi, P. Manuel, X. Tan, Z. Deng, M. Croft, V. Cascos, T. Emge, H. L. Feng, S. Lapidus, C. Jin, M. Wu, M. R. Li, S. Ehrlich, S. Khalid, N. Quackenbush, S. Yu, D. Walker and M. Greenblatt, Chem. Commun., 2019, 55, 3331
DOI: 10.1039/C9CC00038K

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