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Issue 23, 2019
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Efficient visible light-driven water oxidation catalysed by an iron(iv) clathrochelate complex

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Abstract

A water-stable FeIV clathrochelate complex catalyses fast and homogeneous photochemical oxidation of water to dioxygen with a turnover frequency of 2.27 s−1 and a maximum turnover number of 365. An FeV intermediate generated under catalytic conditions is trapped and characterised using EPR and Mössbauer spectroscopy.

Graphical abstract: Efficient visible light-driven water oxidation catalysed by an iron(iv) clathrochelate complex

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Publication details

The article was received on 09 Jan 2019, accepted on 18 Feb 2019 and first published on 18 Feb 2019


Article type: Communication
DOI: 10.1039/C9CC00229D
Chem. Commun., 2019,55, 3335-3338
  • Open access: Creative Commons BY-NC license
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    Efficient visible light-driven water oxidation catalysed by an iron(IV) clathrochelate complex

    S. I. Shylin, M. V. Pavliuk, L. D’Amario, F. Mamedov, J. Sá, G. Berggren and I. O. Fritsky, Chem. Commun., 2019, 55, 3335
    DOI: 10.1039/C9CC00229D

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